For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam extinguishers. Ammonium hydroxide is a caustic inorganic base (an alkaline substance). 0000002366 00000 n Toxic by all routes (ie, inhalation, ingestion, and dermal contact), exposure to this colorless, intensely pungent-smelling liquid may occur from its use in fertilizers, dyes, explosives, plastics, cleansing agents, fibers, and resins. Revised on 04/21/2016 Page 1 of 6 Safety Data Sheet Ammonium Hydroxide 3N 1. Section 3: Composition / Information on Ingredients Ammonium Hydroxide, (1336-21-6), 1-2% as Ammonia Water: (CAS No. Unknown Acute Toxicity (GHS-US) No data available. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls 0000004611 00000 n Health issue . fInhaling Ammonium Hydroxidecan irritate the lungs causing coughing and/or shortness of breath. AMMONIUM HYDROXIDE can be found in 65 products. 0000001303 00000 n 0000000016 00000 n It can be denoted by the symbols NH 3 (aq). It is soluble in water. Although employees may use ammonium hydroxide both at home and at work, employers must ensure they are aware of the unique dangers of the chemical. Evolves toxic gaseous ammonia with strong bases. On burning: release of toxic and corrosive gases/vapours (nitrous vapours). 0000002525 00000 n When dissolved in water, Ammonia forms Ammonium Hydroxide (H5NO). endstream endobj 29 0 obj <. 4 0 obj Used in everything from household cleaners to industrial processes, it is toxic in all solutions. 0000003577 00000 n Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-9402 Signal Word DANGER SECTION 2 â HAZARDS IDENTIFICATION Hazard class: Acute toxicity, oral (Category 4). Strong oxidizers, acids, halogens, salts of silver & zinc [Note: Corrosive to copper & galvanized surfaces.] Causes severe skin burns and eye damage. 0000001926 00000 n Workers in all industries should know that, despite its common usage, ammonia poses health risks and hazards that require proper use of personal protective equipment (PPE) and safe use and handling procedures. 0 colorless liquid with a strong odor and bad taste, Four Steps to Conducting a Job Safety Analysis in the Canadian Workplace, Train over any hazardous chemicals that employees may be exposed to, Train employees to detect and respond ⦠Ammonia (H3N) is a gas. fExposure can irritate the eyes, nose and throat. Search results for 1336-21-6 at Sigma-Aldrich. 'ü¸¥q 0000004083 00000 n Such a precipitate can explode on stirring [MCA Case History 1554 1968]. Take all appropriate precautions. P271 - Use only outdoors or in a well-ventilated area. Source. Reacts extremely violently with dimethyl sulfate [NFPA 491M 1991]. Ammonium hydroxide, ACS reagent, 28-30% solution in water, ACROS Organics⢠CAS=1336-21 ⦠Avoid ammonium hydroxide contact with chemicals such as mercury, chlorine, iodine, bromine, silver oxide or hypochlorites; they can form explosive compounds. 61 0 obj <>stream May adversely affect pH of aquatic ecosystems. 0000018685 00000 n endobj RTECS:BQ9625000 - Ammonium hydroxide - The Registry of Toxic Effects of Chemical Substances | CDC/NIOSH 0000003112 00000 n Print Share on: Evidence. Ammonium hydroxide is not a flammable liquid; however, ammonia gas is flammable. Ammonia can be mixed with water and sold as ammonium hydroxide, or used in compressed gas as anhydrous ammonia (meaning without water). Ammonia: LC50, Water Flea (Daphnia magna): 0.66 mg/L 48 h Persistence and Degradability: Expected to be readily biodegradable. "R}~Q:~pgg'������"���l���/���������O�:OϽV�ޞ�~ @����������zo��7��g;)�Kߜӗ���;�����=�d�������'}z��8}����7w�7?���I�������u��w?ݾw��~�����i�����k���K�^��^'��d4k����˗;�g����_�u_�������L��OC6���($uiz["��Dڻw�#����6����"������UH��8/�?CZ7�����D|z�?���W5M��78����k"^�8�ö����$���p(�?kӴ������ׅL�}��~�Gm�ֽ�{{���>~�O4��v���{���x��?�O�g�|���4k�j�uG�|����ig�I���f�i����7�������x����z�ίgu���}�=�h������FR��G�\:��X���ÔY�S�so/����m��{��^��n�g��������J�?�_����˝��l��R�� ~ ������!J�����s��A���'Y*��ߤ\=���f/�� ��3[��= ����'u~ͻ�/���g�����i���� �_C�|�2��S�A^�����|z��;���^���jy�h>~�� ��{�7? 0000004534 00000 n inhalation, ingestion (solution), skin and/or eye contact (solution/liquid) Symptoms. Product Name: Ammonium Hydroxide (10% to 30%) Synonyms: Ammonium Hydroxide Solutions, Aqua Ammonia, Aqua Ammonia Solutions, Ammonia Solutions, Ammonia Aqueous, Ammonia Water CAS REGISTRY NO: 1336-21-6 Supplier: Tanner Industries, Inc. 735 Davisville Road, Third Floor Southampton, PA 18966 Website: www.tannerind.com Telephone (General): 215-322-1238 0000001700 00000 n : with (some) halogens compounds, with ⦠When employees work with industrial chemicals, they often are not using products they will find at home. The major hazards encountered in the use and handling of ammonium hydroxide stem from its toxicologic properties. Serious Eye Damage/Eye Irritation Category 1. 0000006391 00000 n 0000004305 00000 n AMMONIUM HYDROXIDE reacts exothermically with acids. Tetramethylammonium hydroxide is a solid in the hydrated form or a colorless liquid with a strong ammonia -like odor. xref Ammonia and Ammonium Hydroxide are used in a large variety of products including hair dyes, hair bleaching products, shaving cream and hair grooming products. 0000018893 00000 n 28 34 /Producer(Sub Systems, Inc.)/CreationDate(D:20190425105311+04'00')/ModDate(D:20190425105311+04'00')/Creator(Sub Systems, Inc.) MDL number MFCD00066650 Safety Data Sheet (SDS) SECTION 1 â CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Ammonium Hydroxide 1.1 M - 14.8 M Flinn Scientific, Inc. P.O. X���`I�%&/m�{J�J��t��`$ؐ@������iG#)�*��eVe]f@�흼��{���{���;�N'���?\fdl��J�ɞ!���?~|? 0000001520 00000 n 0000007425 00000 n startxref >> 0000001439 00000 n ýda BL:nCòé [Ö ×-|ëúÀ7LôÿDÄÛÚVíp)J0æs~t@ûãäñVÖêg,0G'¹ ¬bÎmËõ@ÅëæåºS ªÕÛòå0(ÄxÁX,CÝ ü¥F$°üÿÛ Ammonia vapors are released when heated. Environmental Effects: Very toxic to aquatic life. Material uses: Laboratory Reagent. 2.4. Exposure Routes. Although the name ammonium hydroxide suggests an alkali with composition [NH 4 +][OH â], it is actually impossible to isolate samples of NH 4 OH. Ammonium hydroxide is a colorless liquid with a strong odor and bad taste. It is also a highly corrosive chemical and a skin, eye, and respiratory irritant. %%EOF Reacts with aqueous silver nitrate sodium hydroxide to give a black precipitate of silver nitride. Ventilation rates should be matched to conditions. P270 - Do not eat, drink or smoke when using this product. Health Hazard Ammonium hydroxide solutions are alkaline solutions, meaning they have high pH level. 1 0 obj 0 Ammonium hydroxide solution ACS reagent Synonym: Ammonia aqueous, Ammonia water CAS Number 1336-21-6. 0000006157 00000 n Y>ákî'ÅI9bÀrR/OÕIÚÏà÷+aoÁ¶ßï? 0000010276 00000 n Tel: (201) 796-7100. Compare Products: Select up to 4 products. HAZARDS IDENTIFICATION Terra Industries Inc. Terra Centre â 600 Fourth Street Sioux City, Iowa ⦠Compliant with the OSHA Hazard Communication Standard 1910.1200 and aligned with the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Made in the United States of America AMMONIA SOLUTION, STRONG, AMMONIA WATER, AMMONIA, AQUEOUS SOLUTION, AMMONIUM HYDROXIDE, AMMONIUM HYDROXIDE ((NH4)(OH)), AQUA AMMONIUM, HARTSHORN SPIRIT, SPIRIT OF HARTSHORN, and STRONG AMMONIA SOLUTION Safety Data Sheet Ammonium Hydroxide Issue Date: 12/30/2015 V1.0 1. Ammonium Hydroxide / 1336-21-6 39.1% 25 ppm TWA Water / 7732-18-5 60.9% 35 ppm STEL 50 ppm PEL Contains 19% ammonia as NH3 300 ppm IDLH 3. Fair Lawn, NJ 07410. 0000005636 00000 n However, ammonium hydroxide is one exception. 0000019272 00000 n Fisher Scientific. Very toxic to aquatic life . {�k��Ο�(���(�?�s_���/C�V��0�ਇm�l8a���;�����|�1�3m����3~N�֙���y����4�?�4�[��JEL�. P273 - Avoid release to the environment. Conditions to Avoid Avoid ammonium hydroxide contact with chlorine, which forms a chloramine gas, which is a primary skin irritant and sensitizer. 0000012304 00000 n One Reagent Lane. As a result, ammonium hydroxide is a severe eye, skin, and respiratory tract irritant, and readily burns tissue with which it comes in contact. This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). stream 28 0 obj <> endobj 0000003612 00000 n Beilstein/REAXYS Number 3587154 . However concentrated ammonia solutions may give off ammonia vapours. << Possibility of Hazardous Reactions Ammonium hydroxide will react exothermically with acids. The vapors are extremely irritating to the eyes. 0000019076 00000 n *Please select more than one item to compare May cause respiratory irritation. Other Hazards Ammonium hydroxide is very volatile and may release ammonia as a gas. 0000006041 00000 n Incompatibilities & Reactivities. Ammonium hydroxide itself is non-combustible. PRODUCT AND COMPANY IDENTIFICATION Product name: Ammonium Hydroxide ~30% Product code: 05870-16 Supplier: StatLab Medical Products 2090 Commerce Drive McKinney, TX 75069 800-442-3573 972-436-1369 Fax statlab.com Synonym: None. Wear appropriate protective clothing to ⦠Direct contact with the eyes can cause blindness if not washed away immediately within the first 10 seconds. trailer Company. 0000018450 00000 n Ammonia vapor, in concentrations of 16-25% volume by weight in air, is flammable, toxic by inhalation and corrosive. Product:)Ammonium)Hydroxide,)50%)v/v) RevisionDate:)05/18/2016) 6/7) Ecotoxicological Data: Water: Not applicable. The following acute (short-term) health effects may occur immediately or shortly after exposure to Ammonium Hydroxide: fContact can severely irritate and burn the skin and eyes leading to eye damage. SAFETY DATA SHEET: AMMONIUM CHLORIDE - AMMONIUM HYDROXIDE BUFFER TS AMMONIUM CHLORIDE - AMMONIUM HYDROXIDE BUFFER TS A631.7A INTEGRA Chemical Company 24 Hour Emergency Response: CHEMTREC 800 ⦠Product: Ammonium Hydroxide Revision Date: 12/03/2012 4/7 Engineering Controls: Ensure adequate ventilation. It is corrosive to metals and tissue. 3 Effective date : 11.05.2014 Page 2 of 6 Ammonium Hydroxide, 3M Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com P264 - Wash exposed skin thoroughly after handling. Ammonia gas is generally not considered a serious fire or explosion hazard because ammonia/air mixtures are difficult 0000000976 00000 n §ðÔ¶ËÞTzÍW®,£ù¥Ö%|$fFØßÌßznÅO§C¬!¥ÿ£TehXãpýÁ©/yþô@=rÚ Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. Ammonia solution, also known as ammonia water, ammonium hydroxide, ammoniacal liquor, ammonia liquor, aqua ammonia, aqueous ammonia, or (inaccurately) ammonia, is a solution of ammonia in water. PRODUCT AND COMPANY IDENTIFICATION Product Name: Ammonium Hydroxide 3N Synonyms/Generic Names: Aqueous Ammonia; Strong Ammonia Solution; Stronger Ammonia Water Product Number: 8133 Product Use: Industrial, Manufacturing or Laboratory use Manufacturer: Columbus Chemical Industries, Inc. <<0E3A66ABCCE85E48B6E7192D2C7FA130>]>> Level of Concern . 0000013231 00000 n %���� Tetramethylammonium hydroxide (TMAH or TMAOH) is a quaternary ammonium salt with the molecular formula N(CH 3) 4 + OH â.It is commonly encountered as concentrated solutions in water or methanol.The solid and solutions are colorless, or yellowish if impure. %PDF-1.4 For use on containers that store Ammonium Hydroxide to ensure the workplace is aware of the immediate chemical hazards that are present. decomposition products. 0000009368 00000 n Molecular Weight 35.05 . As the nation's health protection agency, CDC saves lives and protects people from health, safety, and security threats. 7732-18-5), 98-99% Section 4: First Aid Measures <> 0000015924 00000 n Ammonium hydroxide is highly toxic whether it is inhaled, ingested, or absorbed through the skin. 0000008433 00000 n ... in this product - not the product itself - compared to other product formulations. %PDF-1.6 %âãÏÓ 0000003840 00000 n 0000011267 00000 n On heating: release of toxic/corrosive/combustible gases/vapour s (ammonia). Concentrated solution violent to explosive reaction with many compounds e.g. The gas is an eye, skin and respiratory irritant. Ammonia reacts with strong oxidizers, acids, halogens (including chlorine bleach), and salts of silver, zinc, copper, and other heavy metals. Linear Formula NH 4 OH . Skin Corrosion/irritation Category 1 B. 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